Chef Tim Says...
Twenty years ago it was rare to find much more than a green bell pepper in grocery stores. The sweet or bell pepper is a member of the Capsicum family, making them a cousin to chili peppers such as jalapenos and habaneros. Red bell peppers are simply green peppers that have been allowed to ripen on the vine longer and are, consequently, sweeter. Yellow, orange and purple varieties are widely available now as well, each with subtly different flavors.

Red, green, and yellow bell peppers.
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Poblanos range from very dark green to almost black. They
are mildly spicy with a heat index of mild to medium. The
darker pepper has a more intense flavor. As poblano peppers
mature they turn a reddish brown. Dried poblanos are known
as Ancho chilis.
Look for peppers that are firm to the touch and have no
dark spots or obvious bruising. One sign of a pepper that
is not fresh is when there are small pits in the skin.
Interestingly, green bell peppers have twice the amount
of vitamin C as oranges and red or yellow bell peppers have
4 times as much.

Poblano pepper.
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To roast peppers, start by setting the oven on broil. Wash
the peppers and place them in the oven about 4 to 6 inches
under the broiler. Check on them every two minutes or so,
turning them one quarter turn at a time until they are well
charred on the outside. You can do this over the burner or
grill but I find that you have to be more careful than with
the broiler.
When the pepper is well charred remove it from the oven
and place in a paper bag. Close the bag and allow the pepper
to cool completely. The skin will then slip off easily and
once sliced open it is seeded just as easily.
One time I was doing a demonstration of a recipe using roasted
peppers and the host asked if he could use bottled red peppers.
The answer is yes. While some are packed in oil, most are
packed in water with a little vinegar. Either way, they rarely
have much, if any, salt. I have tested recipes with fresh
and bottled peppers and there is a difference in the fresh
roasted flavor not coming through as well with the bottled
peppers, but overall they are really good. I have also used
bottled roasted yellow peppers with similar results.

Habanero.
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There are dozens of hot peppers available to you, and if
you are so inclined, there are even hot pepper societies for
the appreciation of these spicy delicacies. Dr. Gourmet recipes
generally call for milder types like anchos, chipotles and
jalapenos.
Chipotles are actually jalapeno chilis that have been smoked
and dried. The intense flavor is spicy and has lovely undertones
of smoke, chocolate and sweet peppers. If the peppers are
not going to cook for very long, I will often soften them
by steaming for about ten minutes.
Usually found in markets, dried chipotles are also sold
packed in cans in adobo, which is a spicy sauce made of vinegar,
dried chili peppers, herbs and spices

Jalapeno pepper.
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The heat of chili peppers is measured in Scoville units,
a scale that was invented by Wilbur L. Scoville in 1912. He
based this on the number of parts of sugar water that it would
take to dilute the extract of chilies to the point that there
is a barely detectable burn. While this seems a bit obsessive
for my taste, pretty much anything over 5,000 scoville units
is hot (let alone the sauces and peppers that advertise themselves
as being 10, 20 or 100 times that hot).
Practically speaking, you will find only a handful of pepper
types in a typical grocery store. The most common in the U.S.
markets (from mild to hot) are:
Mild (1,000 – 2,000
scoville units)
Poblano
Ancho (smoked poblano)
Medium to hot (2,000 – 5,000
scoville units)
Jalapeno
Chipotle (smoked jalapeno)
Serrano
Very Hot (1,000,000 – 3,000,000
scoville units)
Scotch Bonnet
Habanero
Thai
4 ounces peppers = 30 calories, 0g fat, 0g sat fat, 0g mono
fat, 1g protein, 7g carbohydrates, 3mg sodium, 0mg cholesterol